Reading: CHP 12 Coordination Chemistry, Oh Reaction Mechanisms: Sect 12.1 - 12.4
Additional Reading (we will look at three figures in class): Journal of Inorganic Biochemistry Volume 77, Issues 1–2, 1 October 1999, Pages 23-29

PreAssignment: Introduction and Review Movie

12_Oh_CoordRxns.ppt (updated 2014, presented online)

Learning Outcomes:

  1. Be able to interpret Reaction Energy Profiles, using appropriate terminology, describing various types of reaction mechanisms for Oh complexes
  2. Understand the relationship between d-electron configuration rate of ligand substitution (inert vs labile)
  3. Be able to predict the effect of oxidation state, ionic radius, sterics, LFAE, incoming ligand, etc on reactions that proceed by various mechanism types (A, I, D, Ia, Td)

Group Activity - TBD

Problem Set: 12.1, 12.2, 12.3, 12.4, 12.5, 12.8, 12.9 (solutions)

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