Reading: CHP 12 Coordination Chemistry, Oh Reaction Mechanisms: Sect 12.1 - 12.4
Additional Reading (we will look at three figures in class): Journal of Inorganic Biochemistry Volume 77, Issues 1–2, 1 October 1999, Pages 23-29

PreAssignment: Introduction and Review Movie

Materials:
12_Oh_CoordRxns.ppt (updated 2014, presented online)

Learning Outcomes:

  1. Be able to interpret Reaction Energy Profiles, using appropriate terminology, describing various types of reaction mechanisms for Oh complexes
  2. Understand the relationship between d-electron configuration rate of ligand substitution (inert vs labile)
  3. Be able to predict the effect of oxidation state, ionic radius, sterics, LFAE, incoming ligand, etc on reactions that proceed by various mechanism types (A, I, D, Ia, Td)

Group Activity - TBD


Problem Set: 12.1, 12.2, 12.3, 12.4, 12.5, 12.8, 12.9 (solutions)

Reading: 

  • CHP 12 Coordination Chemistry; Chelate Effect - Stereochemistry: Sect 12.4.5
    • Note: We skipped 12.5 stereochemistry of Oh reactions
  • Siderophores (chelation and biological iron transport)

Learning Outcomes:

  • Be able to explain the chelate effect from a kinetic and thermodynamic perspective

Group Activity - 15CoordII_Chelate_2012.pdf

  • Supplements: Slideshow for Stereochemistry of Reactions
  • Be able to predict the possible products of substitution reactions for trans and cis Oh complexes

Exercise 12.2
Problem Set: 12.13, 12.21  (solutions)

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