Reading: CHP 9 Coordination I: Sect 9.1, 9.2, 9.4 (9.3 is for the next assignment)

PreAssignment:

  • Complete problems 1-3 of the Group Activity and Bring to class

Learning Outcomes:

  1. be able to define a coordinate covalent bond
  2. be able to define a ligand as monodentate or chelating
  3. be able to describe the coordination environment (types of ligands and geometry), oxidation state of a coordination compound
  4. be able to match a coordination compound to its name
  5. be able to describe the types of isomers possible for a given compound
  6. identify stereochemistry of chelate rings (ppt movie)

Group Activity - 15CoordI_2012.pdf
- Solutions


Problem Set: 9.1-9.9  (solutions)

Reading: CHP 9 Coordination I, Isomers: Sect 9.3

PreAssignment:

  • PreQuiz

Learning Outcomes:

  1. be able to define a coordinate covalent bond
  2. be able to define a ligand as monodentate or chelating
  3. be able to describe the coordination environment (types of ligands and geometry), oxidation state of a coordination compound
  4. be able to match a coordination compound to its name
  5. be able to describe the types of isomers possible for a given compound
  6. chelate isomers ppt slides

Group Activity - 15CoordI_2012.pdf


Problem Set (4th ed): 9.10, 9.11, 9.12, 9.13, 9.17a, d  (solutions)

Problem Set (5th ed): 9.10, 9.11, 9.12, 9.15, 9.20, 9.21  (solutions)

Reading: CHP 10 Coordination II
Required Supplemental Reading
Sections from Tarr that are similar to supplemental reading 10.3.2, 10.3.3, 10.4.4, 10.5

Interactive CFT for Oh, Td, SqPlanar

PreAssignment:

  • No Preassignment

Learning Outcomes:

  1. use crystal field theory to describe the relative d-orbital energies, spin state, and magnetism of transition metal complexes
    1. Oh, Td, SQ Planar, Tetragonal, SQ Pyramid, TBP 
  2. understand the difference between strong and weak-field ligands
  3. calculate LFSE for Oh and Td complexes
  4. predict the geometries of metal complexes based on LFSE

Group Activity - 15CoordII_CFT_2012.pdf


Exercises: From supplemental reading (20.1, 20.1, 20.3, 20.4, 20.5, 20.8, 20.9)

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