Reading: CHP 7 Solid Structures: Sect 7.1

PreAssignment:

Learning Outcomes:

  1. How to use unit cells to describe solids
  2. Understand close-packed and non close-packed structures
  3. Describe the structures of metals (periodic table of crystal structures)
  4. Describe the structures of simple ionic compounds
  5. Radius ratio

 

Group Activity - 14Solids-basic_2012.pdf


Problem Set (4th ed): 7.1, 7.2, 7.3, 7.4a, 7.4b, 7.5, 7.7, 7.9, 7.12, 7.13 (solutions), Radius of Cu in an FCC lattice.

Problem Set (5th ed): 7.1, 7.2, 7.3, 7.4a, 7.4b, 7.5, 7.7, 7.9, 7.12, 7.13 (solutions), Radius of Cu in an FCC lattice.

 

Reading: CHP 7 Solid Structures: Sect 7.2, 7.3

Additional Reading: Shriver: The electronic structure of solids

Slideshow from Class Lecture

Other Helpful Links

PreAssignment:

Learning Outcomes:

  1. Review Born-Haber Cycle and use it to calculate lattice energies (2 examples: NaCl, CaCl2)
  2. Define Madelung Constant
  3. Describe band structure as a extension of MO theory
  4. Describe the difference in bands for metals, nonmetals, semimetals, and doped materials

Group Activity - 14Solids-bonding_2012.pdf


Problem Set (4th ed): 7.18, 7.19, 7.21, 7.25 (solutions)

Problem Set (5th ed): 7.18, 7.19, 7.21, 7.25 (solutions)

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